Personally, I recommend that you possibly stick with the adult ad network, since that will of course be your target market. Payouts can be high depending on your traffic and clicks etc. I know a few good programs and if you need them just send me a PM and I'll get them to you.
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well i think there are some adult ad affialiates out there. but i think you can just better go to a huge forum like this and ask somebody if he needs advertising. hope there are some people around with an adult site tho ^^