The encoding for Chinese Character love
愛

is

%E6%84%9B

You can go http://blogdigger.com/search?q=%E6%84%9B&sortby=date to make sure.

However, if I type the AscW(sTmp) in visual basice where sTmp is the Chinese Character,

I got

24859

What is the connection between number 24859 to %E6%84%9B

As far as I know hex(24859) is 611B and not E6849b

So, what am I missing here?